I flippin' love the Divine Comedy... but I've always thought that their TW theme felt somewhat out of place.
It's not the worst TW theme, though - that dishonour must surely go to the one used during Carol Vorderman's (brief) time:
Of course, Howard and Maggie presented the show during the period that Paul Hart's trumpet fanfare (posted by RDJ) was in use.
"Channel 5! The channel that brings you England goals!" -- Jonathan Pearce, 31 May 1997